Взаимное влияние лигандов в полусэндвичевых комплексах переходных металлов с пятичленным циклическим ?-лигандом по данным рентгенодифракционных исследований и квантово-химических расчётов
Диссертация
Химия л-комплексов переходных металлов является одним из основных направлений в элементоорганической химии. Развитие данной области наблюдается с конца 50-х годов по настоящее время. Повышенное внимание к л-комплексам обусловлено прежде всего прикладным значением результатов изучения реакций ненасыщенных органических молекул с соединениями переходных металлов. Так установлено, что многие… Читать ещё >
Содержание
- ГЛАВА 1. ПОЛУСЭНДВИЧЕВЫЕ КОМПЛЕКСЫ ПЕРЕХОДНЫХ МЕТАЛЛОВ С ШЕСТИЧЛЕННЫМИ И ПЯТИЧЛЕННЫМИ ЦИКЛИЧЕСКИМИ я-ЛИГАНДАМИ. ЛИТЕРАТУРНЫЙ ОБЗОР
- 1. ПОЛУСЭНДВИЧЕВЫЕ КОМПЛЕКСЫ ПЕРЕХОДНЫХ МЕТАЛЛОВ С
- ШЕСТИЧЛЕННЫМИ ЦИКЛИЧЕСКИМИ л-ЛИГ АНДАМИ
- 1. 1. 1. ТРИКАРБОНИЛ-(л6-БЕНЗО Л) ХРОМ ((г|6-С6Н6)Сг (СО)з)
- 1. 1. 2. Арен замещённые (г|6-СбН5К)Сг (СО)з производные комплекса
- 1. 1. 3. Полусэндвичевые комплексы ЬМ (СО)3, где Ь-шестичленный гетероциклический я-лиганд
- 2. ПОЛУСЭНДВИЧЕВЫЕ КОМПЛЕКСЫ ПЕРЕХОДНЫХ МЕТАЛЛОВ С ПЯТИЧЛЕННЫМИ ЦИКЛИЧЕСКИМИ я-ЛИГАНДАМИ. 39 1.2.1 Цимантрен
- 1. 2. 2. Мэно-замещённые производные цимантрена
- 1. 2. 3. Полусэндвичевые комплексы с пятичленным гетероциклическим я-лигандом
- 3. ПРИМЕНЕНИЕ ТЕОРИИ АМ ДЛЯ ОПИСАНИЯ М-я
- 1. 1. 1. ТРИКАРБОНИЛ-(л6-БЕНЗО Л) ХРОМ ((г|6-С6Н6)Сг (СО)з)
- ВЗАИМОДЕЙСТВИЯ В я-КОМПЛЕКСАХ ПЕРЕХОДНЫХ МЕТАЛЛОВ
- 1. 3. 1. Основные положения теории АМ
- 1. 3. 2. Особенности топологии М-я взаимодействия в комплексах, содержащих нециклические я-лиганды
- 1. 3. 3. Особенности топологии М-я взаимодействия в комплексах, содержащих циклические я-лиганды
- 1. 3. 4. Квантово-топологические дескрипторы связи
- 1. 3. 1. Основные положения теории АМ
- 1. СТРУКТУРНОЕ ИССЛЕДОВАНИЕ ПРОИЗВОДНЫХ 2,5-ДИФЕНИЛФОСФАЦИМАНТРЕНА
- 2. 1. 1. Строение 2,5-дифенилфосфацимантрена (СО)3Мп (т|5-Р112Н2С4Р) (I)
- 2. 1. 2. Строение комплексов [(СО)3Мп (т15-РЬ2Н2С4Р (ОК))РаС1]2, где Я = Ме (2), ЕХ (3), ОСН2СН (Ег)(Ме)
- 2. 1. 3. Строение анионных комплексов
- 2. ПРОЯВЛЕНИЕ ВЗАИМНОГО ВЛИЯНИЯ ЛИГАНДОВ В
- 2. 2. 1. Влияние ориентации Мп (СО)3 фрагмента на геометрические и топологические характеристики 2,5-дифенилфосфацимантрена
- 2. 2. 2. Проявление взаимного влияния лигандов в 2,5-замещённых производных фосфацимантрена
- 2. 2. 3. Проявление взаимного влияния лигандов в 2,5-замещённых производных азацимантрена, трикарбонил-(г|5-тиофен)хрома
- 2. 2. 4. Проявление взаимного влияния лигандов в комплексах феррольного типа
- ГЛАВА 3. Экспериментальная часть
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