Сорбционные материалы с импрегнированными гидразонами для рентгенофлуоресцентного определения тяжелых металлов в водах
Диссертация
Изучены кислотно-основные и комплексообразующие свойства полученных тиосемикарбазонов пиридин-2-альдегида, тиофен-2-альдегида и 5-нитротиофен-2-альдегида, а также 3-бисгуанидина. Установлено, что все эти реагенты являются слабыми кислотами, проявляющими координационную активность по отношению к металлам (Сс12+, Бе3+, Со2+, М2+, Hg2+, РЬ2+) при рН среды ионизации самих регентов. Обоснован выбор… Читать ещё >
Содержание
- 1. Аналитический обзор
- 1. 1. Рентгенофлуоресцентный метод анализа вод. Достоинства и недостатки
- 1. 2. Тиосемикабазоны и гуанилгидразоны в аналитической химии
- 1. 2. 1. Тиосемикарбазоны
- 1. 2. 1. 1. Применение тиосемикарбазонов в спектрофотометрии
- 1. 2. 1. 2. Флуориметрическое определение металлов с использованием тиосемикарбазонов
- 1. 2. 1. 3. Использование тиосемикарбазонов в хроматографических методах анализа
- 1. 2. 1. 4. Тиосемикарбазоны в электрохимических методах анализа
- 1. 2. 1. 5. Гравиметрическое определение металлов с использованием тиосемикарбазонов
- 1. 2. 1. 6. Твердофазное концентрирование
- 1. 2. 2. Гуанилгидразоны
- 1. 2. 1. Тиосемикарбазоны
- 2. 1. Используемое оборудование
- 2. 2. Растворы и реагенты
- 2. 3. Общие методики экспериментов
- 2. 3. 1. Спектрофотометерическое определение металлов
- 2. 3. 2. Синтез исследуемых реагентов
- 2. 3. 3. Определение константы протонирования, состава комплексов и условных констант устойчивости
- 2. 3. 4. Способы получения образцов для рентгенофлуоресцентного определения металлов
- 2. 3. 5. Пробоподготовка образцов природных вод
- 2. 4. Синтез и физико-химическое исследование гидразонов с дополнительными координирующими центрами в альдегидной и гидразинной компоненте
- 2. 5. Исследование кислотно-основных и комплексообразующих свойств реагентов
- 4. 1. Изучение влияния физико-химических параметров на сорбционное извлечение элементов из водных растворов в динамическом режиме
- 4. 1. 1. Влияние кислотности среды на сорбционные характеристики сорбентов
- 4. 1. 2. Влияние кислотности среды на сорбционные характеристики сорбентов
- 4. 2. Установление метрологических характеристик методик концентрирования элементов
- 4. 3. Изучение влияния физико-химических параметров на сорбционное извлечение элементов из водных растворов в статическом режиме и метрологические характеристики статического варианта концентрирования
- 4. 4. Кинетические характеристики сорбционного материала в виде целлюлозных фильтров, импрегнированных реагентом V
- 4. 5. Анализ природных водных объектов
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