Исследование реакций селективного окисления органических соединений пероксидами в присутствии титан-и ванадий-содержащих мезопористых силикатных материалов
Диссертация
Изучено каталитическое окисление метилфенилсульфида (МФС) Н2О2 и трет-бутилгидропероксидом (ТБГП) в метилфенилсульфоксид и метилфенилсульфон в присутствии новых мезопористых мезофазных силикатных материалов V-MMM, Ti-MMM, Ti-MMM-2 и Ti-SBA-15. Установлено, что система V-MMM/H2O2 наиболее активна, однако ионы V (V) вымываются из силикатной матрицы и реакция протекает в объеме раствора. При… Читать ещё >
Содержание
- СПИСОК СОКРАЩЕНИЙ
- ГЛАВА 1. ЛИТЕРАТУРНЫЙ ОБЗОР
- 1. 1. окислители, используемые в процессах жидкофазного селективного окисления
- 1. 2. Классификация пористых материалов, содержащих ионы переходных металлов
- 1. 3. Синтез пористых материалов, содержащих ионы переходных металлов
- 1. 3. 1. Упорядоченные микро-и мезопористые титан- и ванадий-силикатные материалы
- 1. 3. 2. Аморфные мезопористые смешанные оксиды TiOrSiO]
- 1. 4. физико-химические методы исследования титан-силикатных пористых материалов
- 1. 4. 1. Низкотемпературная адсорбция N
- 1. 4. 2. Рентгеновская дифракция (РД)
- 1. 4. 3. Электронная микроскопия./"
- 1. 4. 4. Оптическая спектроскопия диффузного отражения (ДО)
- 1. 4. 5. Инфракрасная спектроскопия (ИК) и спектроскопия комбинационного рассеяния (КР)
- 1. 4. 6. XANES.EXAFS
- 1. 4. 7. Рентгеновская фотоэлектронная спектроскопия (РФЭС)
- 1. 5. Селективное жидкофазное окисление, катализируемое пористыми материалами, содержащими ионы переходных металлов
- 1. 5. 1. Катализ микропористыми титан-силикатными материалами
- 1. 5. 2. Катализ мезопористыми титан-силикатными материалами
- 1. 5. 3. Катализ мезопористыми ванадий-силикатными материалами
- 1. 6. Основные механизмы активации пероксидов ионами переходных металлов
- 1. 6. 1. Общие принципы
- 1. 6. 2. Механизмы окисления системой TS-1/H202.3/
- 1. 7. Каталитическое окисление 2,3,6-триметилфенола
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