Синтез и координационные свойства новых групп хиральных P, N-бидентатных производных фосфористой кислоты и их использование в асимметрическом катализе аллильного замещения
Большинство печатных работ в данной области посвящено /у/-бидентатным фосфинам, но в последнее время появляется все больше публикаций о применении в асимметрическом катализе принципиально иных лигандов — азотсодержащих производных фосфористой кислоты. Они выгодно отличаются от своих фосфиновых аналогов устойчивостью к окислению и легко (в несколько простых стадий) получаются из доступных… Читать ещё >
Содержание
- I. Введение
II. Хирапьные /yV-бидентатные фосфиты, фосфорамидиты и диамидофосфиты в энантиоселективных каталитических процессах (литературный обзор) 7 II. 1. Cu-катализируемое асимметрическое 1,4-сопряженное присоединение Et2Zn к енонам
11.2. Pd-катализируемое асимметрическое аллильное замещение
11.3. Rh-катализируемое асимметрическое гидросилилирование кетонов
11.4. Rh- и Ir-катализируемое асимметрическое гидрирование олефинов
11.5. Rh-катализируемое асимметрическое гидроборирование олефинов
11.6. Rh-катализируемое асимметрическое гидроформилирование олефинов
11.7. Прочие асимметрические процессы, катализируемые комплексами переходных металлов с хиральными фосфитами 47 III. Синтез и координационные свойства новых групп хиральных РД-бидентатных производных фосфористой кислоты и их использование в асимметрическом катализе аллильного замещения (обсуждение результатов) 49 III. 1. /yV-бидентатные фосфопроизводные ферроценсодержащих альдиминов 49 III. 1.1. РД-бидентатные иминодиамидофосфиты с хиральным атомом фосфора 49 III. 1.2. Хиральные РД-бидентатные иминофосфиты 59 III. 1.3. Фосфиты и диамидофосфиты с числом донорных атомов больше двух
111.2. РД-бидентатные фосфопроизводные аминоспиртов с хиральным атомом фосфора
111.3. РД-бидентатные иминодиамидофосфиты на основе планарнохирального цимантрена
111.4. РД-бидентатные лиганды фосфитного типа с хиральной оксазолиновой периферией
III. 5. РД-бидентатные лиганды фосфитного типа с кетиминной периферией на основе ®
-камфоры
IV. Экспериментальная часть
V. Выводы
VI. Литература
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