Развитие новых методов исследования радикальных реакций, моделирующих биологические процессы в растворах
Диссертация
Подавляющее большинство реакций в живых организмах проходит в молекулярно-организованных средах, когда взаимное положение и молекулярная динамика реакционных центров определяется в первую очередь их ближайшим молекулярным окружением. Наиболее хорошо известным примером фотохимической радикальной реакции в молекулярно-организованной среде является процесс разделения зарядов в фотосинтетических… Читать ещё >
Содержание
- Глава I. Экспериментальная часть
- 1. 1. Установка по изучению ХПЯ с временным разрешением
- 1. 2. Разработка датчика спектрометра ЯМР для изучения фото-ХПЯ с высоким временным разрешением
- 1. 3. Математическая обработка экспериментальных данных
- 1. 4. Установки лазерного импульсного фотолиза, ХПЯ в слабых магнитных полях и ЭПР с временным разрешением
- Глава II. Исследование реакции фотоперегруппировки Фриса при фотолизе 1- и 2-нафтилацетатов
- II. 1. Постановка задачи
- 11. 2. Определение квантовых выходов продуктов реакции
- 11. 3. Влияние добавок тушителей на квантовые выходы продуктов реакции
- 11. 4. Сенсибилизированное разложение 1-нафтилацетата (1-NA)
- 11. 5. Лазерный импульсный фотолиз 1-NA и 2-NA
- 11. 6. Исследование эффектов ХПЯ
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