Π Π°Π·ΡΠ°Π±ΠΎΡΠΊΠ° Π²ΡΡΠΎΠΊΠΎΠ°ΠΊΡΠΈΠ²Π½ΡΡ ΠΊΠ°ΡΠ°Π»ΠΈΡΠ΅ΡΠΊΠΈΡ ΡΠΈΡΡΠ΅ΠΌ Π΄Π»Ρ ΡΠ΅Π°ΠΊΡΠΈΠΈ Π³ΠΎΠΌΠΎΡΠΎΡΠ΅ΡΠ°Π½ΠΈΡ Π°ΡΠΈΠ»Π³Π°Π»ΠΎΠ³Π΅Π½ΠΈΠ΄ΠΎΠ² Π² ΡΠΈΠ½ΡΠ΅Π·Π΅ Π°Π½ΡΠ°-ΠΌΠ΅ΡΠ°Π»Π»ΠΎΡΠ΅Π½ΠΎΠ²
Π Π°Π·ΡΠ°Π±ΠΎΡΠ°Π½ ΠΏΡΠ΅ΠΏΠ°ΡΠ°ΡΠΈΠ²Π½ΡΠΉ ΠΌΠ΅ΡΠΎΠ΄ ΡΠΈΠ½ΡΠ΅Π·Π° 3,6-Π΄ΠΈ-/Π³Π³ΡΠ΅"Π³-Π±ΡΡΠΈΠ»ΡΠ»ΡΠΎΡΠ΅Π½Π° — ΠΏΡΠ°ΠΊΡΠΈΡΠ΅ΡΠΊΠΈ Π²Π°ΠΆΠ½ΠΎΠ³ΠΎ Π»ΠΈΠ³Π°Π½Π΄Π° Π΄Π»Ρ ΠΏΠΎΠ»ΡΡΠ΅Π½ΠΈΡ ΡΡΠ΅ΡΠ΅ΠΎΡΠ΅Π»Π΅ΠΊΡΠΈΠ²Π½ΡΡ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠΎΠ² ΠΏΠΎΠ»ΠΈΠΌΠ΅ΡΠΈΠ·Π°ΡΠΈΠΈ ΠΏΡΠΎΠΏΠΈΠ»Π΅Π½Π° ΠΈ Π΄ΡΡΠ³ΠΈΡ ΠΏΡΠΎΡ ΠΈΡΠ°Π»ΡΠ½ΡΡ ΠΎΠ»Π΅ΡΠΈΠ½ΠΎΠ². ΠΡΠ΅Π΄ΠΏΠΎΠ»Π°Π³Π°Π΅ΡΡΡ, ΡΡΠΎ ΠΏΠΎΡΠ»Π΅ ΠΎΠΏΡΠΈΠΌΠΈΠ·Π°ΡΠΈΠΈ ΡΠΏΠΎΡΠΎΠ±ΠΎΠ² Π²ΡΠ΄Π΅Π»Π΅Π½ΠΈΡ ΠΈ ΠΎΡΠΈΡΡΠΊΠΈ ΠΏΡΠ΅Π΄Π»ΠΎΠΆΠ΅Π½Π½ΡΠΉ ΠΌΠ΅ΡΠΎΠ΄ ΠΎΠ±Π΅ΡΠΏΠ΅ΡΠΈΡ ΠΏΡΠ°ΠΊΡΠΈΡΠ΅ΡΠΊΠΈ ΠΊΠΎΠ»ΠΈΡΠ΅ΡΡΠ²Π΅Π½Π½ΡΠΉ Π²ΡΡ ΠΎΠ΄ ΠΊΠΎΠ½Π΅ΡΠ½ΠΎΠ³ΠΎ ΠΏΡΠΎΠ΄ΡΠΊΡΠ° Π½Π° ΡΡΠΈ ΡΡΠ°Π΄ΠΈΠΈ, ΠΈΡΡ ΠΎΠ΄Ρ ΠΈΠ· Π΄ΠΈΡΠ΅Π½ΠΈΠ»ΠΌΠ΅ΡΠ°Π½Π°. Π¦Π΅Π»ΡΡ… Π§ΠΈΡΠ°ΡΡ Π΅ΡΡ >
- Π‘ΠΎΠ΄Π΅ΡΠΆΠ°Π½ΠΈΠ΅
- ΠΡΠ΄Π΅ΡΠΆΠΊΠ°
- ΠΠΈΡΠ΅ΡΠ°ΡΡΡΠ°
- ΠΡΡΠ³ΠΈΠ΅ ΡΠ°Π±ΠΎΡΡ
- ΠΠΎΠΌΠΎΡΡ Π² Π½Π°ΠΏΠΈΡΠ°Π½ΠΈΠΈ
Π‘ΠΎΠ΄Π΅ΡΠΆΠ°Π½ΠΈΠ΅
- Π‘ΠΏΠΈΡΠΎΠΊ ΡΠΎΠΊΡΠ°ΡΠ΅Π½ΠΈΠΉ
- 1. ΠΠ²Π΅Π΄Π΅Π½ΠΈΠ΅
- 2. ΠΠΈΡΠ΅ΡΠ°ΡΡΡΠ½ΡΠΉ ΠΎΠ±Π·ΠΎΡ
- 2. 1. Π‘ΠΈΠ½ΡΠ΅Π· Π‘Π³-ΡΠΈΠΌΠΌΠ΅ΡΡΠΈΡΠ½ΡΡ
Π°ΡΡΠ°-ΠΌΠ΅ΡΠ°Π»Π»ΠΎΡΠ΅Π½ΠΎΠ² ΠΏΠΎΠ΄Π³ΡΡΠΏΠΏΡ ΡΠΈΡΠ°Π½Π° ΠΈ ΡΠ²ΠΎΠΉΡΡΠ²Π° ΡΠΎΠΎΡΠ²Π΅ΡΡΡΠ²ΡΡΡΠΈΡ
ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠΎΠ² ΠΏΠΎΠ»ΠΈΠΌΠ΅ΡΠΈΠ·Π°ΡΠΈΠΈ
- 2. 1. 2. ΠΡΠ°ΠΏΡ ΡΠΎΠ·Π΄Π°Π½ΠΈΡ ΠΌΠ΅ΡΠ°Π»Π»ΠΎΡΠ΅Π½ΠΎΠ²ΡΡ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠΎΠ² ΠΏΠΎΠ»ΠΈΠΌΠ΅ΡΠΈΠ·Π°ΡΠΈΠΈ ΠΎΠ»Π΅ΡΠΈΠ½ΠΎΠ²
- 2. 1. 3. Π Π°Π·Π²ΠΈΡΠΈΠ΅ ΠΈΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΠΉ ΠΏΠΎΠ»ΠΈΠΌΠ΅ΡΠΈΠ·Π°ΡΠΈΠΈ ΠΏΡΠΎΠΏΠΈΠ»Π΅Π½Π° Π½Π° Π‘Π³-ΡΠΈΠΌΠΌΡΡΡΠΈΡΠ½ΡΡ ΡΠ½ΡΡ-ΠΌΠ΅ΡΠ°Π»Π»ΠΎΡΠ΅Π½Π°Ρ ΠΏΠΎΠ΄Π³ΡΡΠΏΠΏΡ ΡΠΈΡΠ°Π½Π°
- 2. 1. 4. ΠΠ΅ΡΠΎΠ΄ΠΎΠ»ΠΎΠ³ΠΈΠΈ ΡΡΠ΅ΡΠ΅ΠΎΡΠ΅Π»Π΅ΠΊΡΠΈΠ²Π½ΠΎΠ³ΠΎ ΡΠΈΠ½ΡΠ΅Π·Π° Π°Π½ΡΠΉΠ³-ΠΌΠ΅ΡΠ°Π»Π»ΠΎΡΠ΅Π½ΠΎΠ² ΠΏΠΎΠ΄Π³ΡΡΠΏΠΏΡ ΡΠΈΡΠ°Π½Π°
- 2. 1. 4. 1. ΠΠ°ΡΡΠΈΡΠΎΠ²Π°Π½ΠΈΠ΅ Π·Π°ΠΌΠ΅ΡΡΠΈΡΠ΅Π»Π΅ΠΉ Π², Π° -ΠΏΠΎΠ»ΠΎΠΆΠ΅Π½ΠΈΠΈ ΠΊ ΠΌΠΎΡΡΠΈΠΊΠΎΠ²ΠΎΠΌΡ ΡΡΠ°Π³ΠΌΠ΅Π½ΡΡ
- 2. 1. 4. 2. ΠΠ°ΡΡΠΈΡΠΎΠ²Π°Π½ΠΈΠ΅ ΡΡΡΡΠΊΡΡΡΡ ΠΌΠΎΡΡΠΈΠΊΠΎΠ²ΠΎΠ³ΠΎ ΡΡΠ°Π³ΠΌΠ΅Π½ΡΠ°
- 2. 1. 4. 3. ΠΡΠΈΠΌΠ΅Π½Π΅Π½ΠΈΠ΅ ΡΡΠ΅ΡΠ΅ΠΎΡΠ΅Π³ΡΠ»ΠΈΡΡΡΡΠΈΡ Π»ΠΈΠ³Π°Π½Π΄ΠΎΠ² 28 2.2, ΠΠΎΠΌΠΎΡΠΎΡΡΡΠ°Π½ΠΈΠ΅ Π°ΡΠΈΠ»Π³Π°Π»ΠΎΠ³Π΅Π½ΠΈΠ΄ΠΎΠ² Π½Π° Π½ΠΈΠΊΠ΅Π»Π΅Π²ΡΡ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠ°Ρ
- 2. 2. 1. ΠΠΎΠΌΠΎΡΠΎΡΠ΅ΡΠ°Π½ΠΈΠ΅ Π°ΡΠΈΠ»Π³Π°Π»ΠΎΠ³Π΅Π½ΠΈΠ΄ΠΎΠ² Π² ΠΏΡΠΈΡΡΡΡΡΠ²ΠΈΠΈ ΡΡΠ΅Ρ
ΠΈΠΎΠΌΠ΅ΡΡΠΈΡΠ΅ΡΠΊΠΈΡ
ΠΊΠΎΠ»ΠΈΡΠ΅ΡΡΠ² Π½ΠΈΠΊΠ΅Π»Π΅Π²ΡΡ
ΠΊΠΎΠΌΠΏΠ»Π΅ΠΊΡΠΎΠ²
- 2. 2. 1. 1. ΠΡΠΏΠΎΠ»ΡΠ·ΠΎΠ²Π°Π½ΠΈΠ΅ ΠΊΠΎΠΌΠΏΠ»Π΅ΠΊΡΠΎΠ² Ni (0)
- 2. 2. 1. 2. ΠΡΠΏΠΎΠ»ΡΠ·ΠΎΠ²Π°Π½ΠΈΠ΅ ΡΠΈΠ½ΠΊΠ° ΠΈΠ»ΠΈ Π΄ΡΡΠ³ΠΈΡ Π²ΠΎΡΡΡΠ°Π½ΠΎΠ²ΠΈΡΠ΅Π»Π΅ΠΉ
- 2. 2. 2. ΠΠΎΠΌΠΎΡΠΎΡΠ΅ΡΠ°Π½ΠΈΠ΅ Π°ΡΠΈΠ»Π³Π°Π»ΠΎΠ³Π΅Π½ΠΈΠ΄ΠΎΠ² Π² ΠΏΡΠΈΡΡΡΡΡΠ²ΠΈΠΈ ΠΊΠ°ΡΠ°Π»ΠΈΡΠΈΡΠ΅ΡΠΊΠΈΡ
ΠΊΠΎΠ»ΠΈΡΠ΅ΡΡΠ² Π½ΠΈΠΊΠ΅Π»Π΅Π²ΡΡ
ΠΊΠΎΠΌΠΏΠ»Π΅ΠΊΡΠΎΠ²
- 2. 2. 2. 1. ΠΡΠΏΠΎΠ»ΡΠ·ΠΎΠ²Π°Π½ΠΈΠ΅ ΡΠΈΠ½ΠΊΠ° Π² ΠΊΠ°ΡΠ΅ΡΡΠ²Π΅ Π²ΠΎΡΡΡΠ°Π½ΠΎΠ²ΠΈΡΠ΅Π»Ρ
- 2. 2. 2. 2. ΠΡΠΏΠΎΠ»ΡΠ·ΠΎΠ²Π°Π½ΠΈΠ΅ Π΄ΡΡΠ³ΠΈΡ Π²ΠΎΡΡΡΠ°Π½ΠΎΠ²ΠΈΡΠ΅Π»Π΅ΠΉ
- 2. 2. 2. 3. ΠΠ»Π΅ΠΊΡΡΠΎΠ²ΠΎΡΡΡΠ°Π½ΠΎΠ²ΠΈΡΠ΅Π»ΡΠ½ΠΎΠ΅ Π³ΠΎΠΌΠΎ- ΠΈ ΠΊΡΠΎΡΡ-ΡΠΎΡΠ΅ΡΠ°Π½ΠΈΠ΅ Π°ΡΠΈΠ»Π³Π°Π»ΠΎΠ³Π΅Π½ΠΈΠ΄ΠΎΠ²
- 2. 2. 3. ΠΡΠΏΠΎΠ»ΡΠ·ΠΎΠ²Π°Π½ΠΈΠ΅ Π½ΠΈΠΊΠ΅Π»Π΅Π²ΠΎΠ³ΠΎ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠ° Π±Π΅Π· ΡΠΎΠ²ΠΎΡΡΡΠ°Π½ΠΎΠ²ΠΈΡΠ΅Π»Ρ
- 2. 2. 4. ΠΠ»ΠΈΠ³ΠΎΠΌΠ΅ΡΠΈΠ·Π°ΡΠΈΡ ΠΈ ΠΏΠΎΠ»ΠΈΠΌΠ΅ΡΠΈΠ·Π°ΡΠΈΡ Π°ΡΠΈΠ»Π΄ΠΈΠ³Π°Π»ΠΎΠ³Π΅ΠΈΠΈΠ΄ΠΎΠ² Π½Π° Π½ΠΈΠΊΠ΅Π»Π΅Π²ΡΡ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠ°Ρ
- 2. 1. Π‘ΠΈΠ½ΡΠ΅Π· Π‘Π³-ΡΠΈΠΌΠΌΠ΅ΡΡΠΈΡΠ½ΡΡ
Π°ΡΡΠ°-ΠΌΠ΅ΡΠ°Π»Π»ΠΎΡΠ΅Π½ΠΎΠ² ΠΏΠΎΠ΄Π³ΡΡΠΏΠΏΡ ΡΠΈΡΠ°Π½Π° ΠΈ ΡΠ²ΠΎΠΉΡΡΠ²Π° ΡΠΎΠΎΡΠ²Π΅ΡΡΡΠ²ΡΡΡΠΈΡ
ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠΎΠ² ΠΏΠΎΠ»ΠΈΠΌΠ΅ΡΠΈΠ·Π°ΡΠΈΠΈ
- 3. ΠΠ±ΡΡΠΆΠ΄Π΅Π½ΠΈΠ΅ ΡΠ΅Π·ΡΠ»ΡΡΠ°ΡΠΎΠ²
- 3. 1. Π‘ΠΈΠ½ΡΠ΅Π· Π΄ΠΈΠΌΠ΅ΡΠΈΠ»ΡΠΈΠ»ΠΈΠ»Π΅Π½ («/5−3,6-Π΄ΠΈ-/ΠΈ/-Π΅/ΠΈ-Π±ΡΡΠΈΠ»ΡΠ»ΡΠΎΡΠ΅Π½ΠΈΠ»)("/5−2-ΠΌΠ΅ΡΠΈΠ»-4-Π±ΡΠΎΠΌΠΎΠΈΠ½Π΄Π΅Π½ΠΈΠ»)ΡΠΈΡΠΊΠΎΠ½ΠΈΠΉ Π΄ΠΈΡ
Π»ΠΎΡΠΈΠ΄Π°
- 3. 1. 1. Π Π°Π·ΡΠ°Π±ΠΎΡΠΊΠ° ΠΌΠ΅ΡΠΎΠ΄Π° ΡΠΈΠ½ΡΠ΅Π·Π° 3,6-Π΄ΠΈΡΡΠ΅ΡΠ±ΡΡΠΈΠ»ΡΠ»ΡΠΎΡΠ΅Π½Π°
- 3. 1. 1. 1. ΠΠ½ΡΡΡΠΈΠΌΠΎΠ»Π΅ΠΊΡΠ»ΡΡΠ½ΠΎΠ΅ Π³ΠΎΠΌΠΎΡΠΎΡΠ΅ΡΠ°Π½ΠΈΠ΅ 2,2'-Π΄ΠΈΠ±ΡΠΎΠΌΠΎ-4,4'-Π΄ΠΈΡΡΠ΅ΡΠ±ΡΡΠΈΠ»Π΄ΠΈΡΠ΅Π½ΠΈΠ»ΠΌΠ΅ΡΠ°Π½Π°
- 3. 1. 1. 1. 1. ΠΡΠΈΠΌΠ΅Π½Π΅Π½ΠΈΠ΅ Π Π Π¬Π· Π² ΠΊΠ°ΡΠ΅ΡΡΠ²Π΅ Π»ΠΈΠ³Π°Π½Π΄Π° Π² ΡΠ΅Π°ΠΊΡΠΈΠΈ Π³ΠΎΠΌΠΎΡΠΎΡΠ΅ΡΠ°Π½ΠΈΡ
- 3. 1. 1. 1. 2. ΠΡΠΈΠΌΠ΅Π½Π΅Π½ΠΈΠ΅ Π΄ΡΡΠ³ΠΈΡ ΡΠΎΡΡΠΈΠ½ΠΎΠ²ΡΡ Π»ΠΈΠ³Π°Π½Π΄ΠΎΠ²
- 3. 1. 1. 1. 3. ΠΡΠΈΠΌΠ΅Π½Π΅Π½ΠΈΠ΅ Π°ΠΌΠΈΠ½ΠΎΠ² Π² ΠΊΠ°ΡΠ΅ΡΡΠ²Π΅ Π»ΠΈΠ³Π°Π½Π΄ΠΎΠ²
- 3. 1. 1. 1. 4. ΠΡΠΈΠΌΠ΅Π½Π΅Π½ΠΈΠ΅ Π΄ΠΈΠΈΠΌΠΈΠ½ΠΎΠ² Π² ΠΊΠ°ΡΠ΅ΡΡΠ²Π΅ Π»ΠΈΠ³Π°Π½Π΄ΠΎΠ²
- 3. 1. 2. Π‘ΠΈΠ½ΡΠ΅Π· Π΄ΠΈΠΌΠ΅ΡΠΈΠ»ΡΠΈΠ»ΠΈΠ»Π΅Π½ (^5−3,6-Π΄ΠΈ-ΠΈ|/7Π΅Ρ-Π±ΡΡΠΈΠ»ΡΠ»ΡΠΎΡΠ΅Π½-9-ΠΈΠ»)(^5−2-ΠΌΠ΅ΡΠΈΠ»Π³4-Π±ΡΠΎΠΌΠΎΠΈΠ½Π΄Π΅Π½-1-ΠΈΠ»)ΡΠΈΡΠΊΠΎΠ½ΠΈΠΉ Π΄ΠΈΡ Π»ΠΎΡΠΈΠ΄Π°
- 3. 1. 1. Π Π°Π·ΡΠ°Π±ΠΎΡΠΊΠ° ΠΌΠ΅ΡΠΎΠ΄Π° ΡΠΈΠ½ΡΠ΅Π·Π° 3,6-Π΄ΠΈΡΡΠ΅ΡΠ±ΡΡΠΈΠ»ΡΠ»ΡΠΎΡΠ΅Π½Π°
- 3. 2. Π‘ΠΈΠ½ΡΠ΅Π· ΠΌΠ΅ΡΠ°Π»Π»ΠΎΡΠ΅Π½ΠΎΠ² Π½Π° ΠΎΡΠ½ΠΎΠ²Π΅ Π³Π΅Π»ΠΈΡΠ΅Π½ΠΎΠ²ΡΡ
Π»ΠΈΠ³Π°Π½Π΄ΠΎΠ²
- 3. 2. 1. Π‘ΠΈΠ½ΡΠ΅Π· 2,2'-Π΄ΠΈΠΌΠ΅ΡΠΈΠ»-Π¨Π'17−6,9'-Π±ΠΈΡΠΈΠΊΠ»ΠΎΠΏΠ΅Π½ΡΠ°[Π°]Π½Π°ΡΡΠ°Π»ΠΈΠ½Π°
- 3. 2. 1. 1. Π‘ΠΈΠ½ΡΠ΅Π· 9-Π±ΡΠΎΠΌΠΎ-2-ΠΌΠ΅ΡΠΈΠ»-1Π-ΡΠΈΠΊΠ»ΠΎΠΏΠ΅Π½ΡΠ°[Π°]Π½Π°ΡΡΠ°Π»ΠΈΠ½Π°
- 3. 2. 1. 2. Π‘ΠΈΠ½ΡΠ΅Π· Π½Π°ΡΡΠ°Π»ΠΈΠ½ΠΎΠ²ΠΎΠ³ΠΎ Π»ΠΈΠ³Π°Π½Π΄Π°
- 3. 2. 2. Π Π°Π·ΡΠ°Π±ΠΎΡΠΊΠ° ΠΏΠΎΠ΄Ρ ΠΎΠ΄ΠΎΠ² ΠΊ ΡΠΈΠ½ΡΠ΅Π·Ρ ΠΌΠ΅ΡΠΎΠΊΡΠΈΠ½Π°ΡΡΠ°Π»ΠΈΠ½ΠΎΠ²ΠΎΠ³ΠΎ Π»ΠΈΠ³Π°Π½Π΄Π°
- 3. 2. 3. Π‘ΠΈΠ½ΡΠ΅Π· Π±Π΅Π½Π·ΠΎΡΠΈΠΎΡΠ΅Π½ΠΎΠ²ΠΎΠ³ΠΎ Π»ΠΈΠ³Π°Π½Π΄Π°
- 3. 2. 3. 1. Π‘ΠΈΠ½ΡΠ΅Π· 4-Π±ΡΠΎΠΌΠΎΠ±Π΅Π½Π·ΠΎ[Π¬]ΡΠΈΠΎΡΠ΅Π½Π°
- 3. 2. 3. 2. Π‘ΠΈΠ½ΡΠ΅Π· 8-Π±ΡΠΎΠΌΠΎ-2-ΠΌΠ΅ΡΠΈΠ»-ΠΠ-Π±Π΅Π½Π·ΠΎ[Πͺ]ΡΠΈΠΊΠ»ΠΎΠΏΠ΅Π½ΡΠ°[Ρ1]ΡΠΈΠΎΡΠ΅Π½Π°
- 3. 2. 3. 3. Π‘ΠΈΠ½ΡΠ΅Π· ΠΌΠΎΡΡΠΈΠΊΠΎΠ²ΠΎΠ³ΠΎ Π»ΠΈΠ³Π°Π½Π΄Π°
- 3. 2. 4. Π‘ΠΈΠ½ΡΠ΅Π· ΠΊΠΎΠΌΠΏΠ»Π΅ΠΊΡΠΎΠ² Ρ Π»ΠΈΠ³Π°Π½Π΄Π°ΠΌΠΈ Π³Π΅Π»ΠΈΡΠ΅Π½ΠΎΠ²ΠΎΠ³ΠΎ ΡΠΈΠΏΠ°
- 3. 2. 5. ΠΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΠ΅ ΡΡΡΡΠΊΡΡΡΡ ΠΌΠ΅ΡΠ°Π»Π»ΠΎΡΠ΅Π½ΠΎΠ² Ρ Π»ΠΈΠ³Π°Π½Π΄Π°ΠΌΠΈ Π³Π΅Π»ΠΈΡΠ΅Π½ΠΎΠ²ΠΎΠ³ΠΎ ΡΠΈΠΏΠ°
- 3. 2. 1. Π‘ΠΈΠ½ΡΠ΅Π· 2,2'-Π΄ΠΈΠΌΠ΅ΡΠΈΠ»-Π¨Π'17−6,9'-Π±ΠΈΡΠΈΠΊΠ»ΠΎΠΏΠ΅Π½ΡΠ°[Π°]Π½Π°ΡΡΠ°Π»ΠΈΠ½Π°
- 3. 1. Π‘ΠΈΠ½ΡΠ΅Π· Π΄ΠΈΠΌΠ΅ΡΠΈΠ»ΡΠΈΠ»ΠΈΠ»Π΅Π½ («/5−3,6-Π΄ΠΈ-/ΠΈ/-Π΅/ΠΈ-Π±ΡΡΠΈΠ»ΡΠ»ΡΠΎΡΠ΅Π½ΠΈΠ»)("/5−2-ΠΌΠ΅ΡΠΈΠ»-4-Π±ΡΠΎΠΌΠΎΠΈΠ½Π΄Π΅Π½ΠΈΠ»)ΡΠΈΡΠΊΠΎΠ½ΠΈΠΉ Π΄ΠΈΡ
Π»ΠΎΡΠΈΠ΄Π°
Π‘ΠΏΠΈΡΠΎΠΊ ΡΠΎΠΊΡΠ°ΡΠ΅Π½ΠΈΠΉ
ΠΠΠ ΠΌΠ΅ΡΠΈΠ»Π°Π»ΡΠΌΠΎΠΊΡΠ°Π½
Mw ΠΌΠΎΠ»Π΅ΠΊΡΠ»ΡΡΠ½Π°Ρ ΠΌΠ°ΡΡΠ°
Π‘Ρ ΡΠΈΠΊΠ»ΠΎΠΏΠ΅Π½ΡΠ°Π΄ΠΈΠ΅Π½ΠΈΠ»
Ind ΠΈΠ½Π΄Π΅Π½ΠΈΠ»
IndH4 ΡΠ΅ΡΡΠ°Π³ΠΈΠ΄ΡΠΎΠΈΠ½Π΄Π΅Π½ΠΈΠ»
Mt ΠΌΠ΅ΡΠ°Π»Π»
ΠΠΠ‘Π Π΄ΠΈΠΌΠ΅ΡΠΈΠ»ΡΡΠ»ΡΡΠΎΠΊΡΠΈΠ΄
ΠΠΠ Π΄ΠΈΠΌΠ΅ΡΠΎΠΊΡΠΈΡΡΠ°Π½ Π’ΠΠ€, THF ΡΠ΅ΡΡΠ°Π³ΠΈΠ΄ΡΠΎΡΡΡΠ°Π½
Tf20 Π°Π½Π³ΠΈΠ΄ΡΠΈΠ΄ ΡΡΠΈΡΡΠΎΡΠΌΠ΅ΡΠ°Π½ΡΡΠ»ΡΡΠΎΠ½ΠΎΠ²ΠΎΠΉ ΠΊΠΈΡΠ»ΠΎΡΡ
BIPOL Π±ΠΈΡΠ΅Π½ΠΎΠ», Π±ΠΈΡΠ΅Π½ΠΈΠ»-2,2'-Π΄ΠΈΠΎΠ»
BINOL Π±ΠΈΠ½Π°ΡΡΠΎΠ», 1,1'-Π±ΠΈΠ½Π°ΡΡΠΈΠ»-2,2'-Π΄ΠΈΠΎΠ»
TMEDA !Π§, 1Π§, 1Π§', 1Π£-ΡΠ΅ΡΡΠ°ΠΌΠ΅ΡΠΈΠ»ΡΡΠΈΠ»Π΅Π½Π΄ΠΈΠ°ΠΌΠ½Π½
ΠΠΠΠ₯ ΠΡΡΠΎΠΊΠΎΡΡΡΠ΅ΠΊΡΠΈΠ²Π½Π°Ρ ΠΆΠΈΠ΄ΠΊΠΎΡΡΠ½Π°Ρ Ρ ΡΠΎΠΌΠ°ΡΠΎΠ³ΡΠ°ΡΠΈΡ p-TosOH ΠΏ-ΡΠΎΠ»ΡΠΎΠ»ΡΡΠ»ΡΡΠΎΠΊΠΈΡΠ»ΠΎΡΠ° Π³ Π³ΠΎΠ΄, Π³ΡΠ°ΠΌΠΌ
ΠΡ Π³Π΅ΡΡ Ρ ΡΠΈΠ½Π³Π»Π΅Ρ, ΡΠΈΠ»ΡΠ½ΡΠΉ Π΄ Π΄ΡΠ±Π»Π΅Ρ Ρ ΡΡΠΈΠΏΠ»Π΅Ρ ΠΊΠ² ΠΊΠ²Π°Π΄ΡΡΠΏΠ»Π΅Ρ ΠΌ ΠΌΡΠ»ΡΡΠΈΠΏΠ»Π΅Ρ
ΠΠ - Π΄ΡΡΠ³ΠΎΠΉ
ΠΠ ΠΈΠ½ΡΡΠ°ΠΊΡΠ°ΡΠ½ΡΠΉ ΠΈΡΡ . ΠΈΡΡ ΠΎΠ΄Π½ΠΎΠ΅ ΠΊΠΎΠ»-Π²ΠΎ ΠΊΠΎΠ»ΠΈΡΠ΅ΡΡΠ²ΠΎ
J ΠΊΠΎΠ½ΡΡΠ°Π½ΡΠ° ΡΠΏΠΈΠ½-ΡΠΏΠΈΠ½ΠΎΠ²ΠΎΠ³ΠΎ Π²Π·Π°ΠΈΠΌΠΎΠ΄Π΅ΠΉΡΡΠ²ΠΈΡ
ΠΠΡ ΠΌΠ΅Π³Π°Π³Π΅ΡΡ ΠΌ.Π΄. ΠΌΠΈΠ»Π»ΠΈΠΎΠ½Π½Π°Ρ Π΄ΠΎΠ»Ρ ΠΌΠ» ΠΌΠΈΠ»Π»ΠΈΠ»ΠΈΡΡ ΠΌΠΎΠ». ΠΌΠΎΠ»ΡΠ½ΡΠΉ ΡΠ» ΡΠ»Π°Π±ΡΠΉ ΡΠΌ ΡΠ°Π½ΡΠΈΠΌΠ΅ΡΡ ΡΠ΅ΠΌΠΏ. ΡΠ΅ΠΌΠΏΠ΅ΡΠ°ΡΡΡΠ° ΡΡΠ΅Ρ ΡΡΠ΅ΡΠΈΡΠ½ΡΠΌ
Π’ΠΊΠΈΠΏ. ΡΠ΅ΠΌΠΏΠ΅ΡΠ°ΡΡΡΠ° ΠΊΠΈΠΏΠ΅Π½ΠΈΡ
Π’ΠΏΠ». ΡΠ΅ΠΌΠΏΠ΅ΡΠ°ΡΡΡΠ° ΠΏΠ»Π°Π²Π»Π΅Π½ΠΈΡ ΡΡ, ΡΡΠΈΡΠ΅Π½Π½ΡΠΉ Ρ ΡΠ°Ρ ΡΠΊΠ². ΡΠΊΠ²ΠΈΠ²Π°Π»Π΅Π½Ρ ΡΠΊΡΠΏ. ΡΠΊΡΠΏΠ΅ΡΠΈΠΌΠ΅Π½ΡΠ°Π»ΡΠ½Π°Ρ
Π―ΠΠ ΡΠ΄Π΅ΡΠ½ΡΠΉ ΠΌΠ°Π³Π½ΠΈΡΠ½ΡΠΉ ΡΠ΅Π·ΠΎΠ½Π°Π½Ρ
ΠΡ Π°ΡΠ΅ΡΠΈΠ»
Me ΠΌΠ΅ΡΠΈΠ»
Et ΡΡΠΈΠ»
Π Π³ ΠΏΡΠΎΠΏΠΈΠ»
ΠΠΈ Π±ΡΡΠΈΠ»
ΠΠ³ Π°ΡΠ½Π»
Ph ΡΠ΅Π½ΠΈΠ» ΠΏ Π½ΠΎΡΠΌΠ°Π»ΡΠ½ΡΠΉ i ΠΈΠ·ΠΎ t ΡΡΠ΅ΡΠΈΡΠ½ΡΠΉ
Π‘ΠΏΠΈΡΠΎΠΊ Π»ΠΈΡΠ΅ΡΠ°ΡΡΡΡ
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