Синтез и самоорганизация амфифильных блокградиентных сополимеров стирола и акриловой кислоты
Диссертация
Наиболее ярким примером амфифильных сополимеров образующих различные агрегаты в водной среде, служит блок-сополимер полистиролполиакриловая кислота (ПС-б-ПАК). Известно, что такие сополимеры не способны к формированию динамических мицелл. Попытка создать такие объекты на основе градиентных или блок-статистических сополимеров также оказалась неудачной. Можно было ожидать, что получить динамические… Читать ещё >
Содержание
- 1. Литературный обзор
- 1. 1. Контролируемая радикальная полимеризация в присутствии нитроксилов
- 1. 2. Свойства амфифильных ионогенных сополимеров в водных растворах
- 2. Экспериментальная часть
- 2. 1. Объекты исследования
- 2. 2. Синтез полиакриловой кислоты
- 2. 3. Определение констант сополимеризации стирола и акриловой кислоты
- 2. 4. Определение констант скорости распада аддуктов ПАК-SGl, ПС-SGl в различных растворителях
- 2. 5. Определение констант скорости рекомбинации макрорадикалов СТ, АК и МА с нитроксилами SG1, ТЕМПО и гальвиноксилом
- 2. 6. Синтез диблок-сополимеров стирола и акриловой кислоты
- 2. 7. Синтез триблок-сополимеров стирола и акриловой кислоты
- 2. 8. Методы исследования
- 3. 1. Синтез ди- и триблок-градиентных сополимеров стирола и акриловой кислоты методом контролируемой радикальной полимеризации с участием нитроксила SG1. Определение кинетических параметров процесса
- 3. 1. 1. Определение зависимости молекулярной массы продукта от конверсии
- 3. 1. 2. Определение кинетических параметров, характеризующих механизм полимеризации: константы скорости распада и константы скорости рекомбинации
- 3. 1. 3. Определение констант сополимеризации стирола и акриловой кислоты
- 3. 2. Изучение самоорганизации в водном растворе диблок-градиентных сополимеров стирола и акриловой кислоты
- 3. 3. Изучение самоорганизации в водном растворе триблок-градиентных сополимеров стирола и акриловой кислоты
- 3. 3. 1. Влияние самоорганизации на структурные свойства раствора
- 3. 3. 2. Влияние самоорганизации на динамические (реологические) свойства раствора
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