Диспропорционирование кумола на цеолитных катализаторах с комбинированной микро-мезопористой структурой
Диссертация
В связи с этим, в задачи настоящей работы входило установление основных закономерностей реакции диспропорционирования кумола на новых цеолитных катализаторах с комбинированной микро-мезопористой структурой, а также разработка на основе этих систем высокоэффективного катализатора диспропорционирования кумола, обеспечивающего высокую конверсию кумола, селективность по продуктам… Читать ещё >
Содержание
- ОБЗОР ЛИТЕРАТУРЫ
- Глава 1. Диспропорционирование, а л кил ароматических углеводородов
- 1. 1. Диспропорционирование алкилароматических углеводородов с использованием гомогенных катализаторов
- 1. 2. Диспропорционирование алкилароматических углеводородов на гетерогенных катализаторах
- 1. 3. Диспропорционирование алкилароматических углеводородов на цеолитных катализаторах
- 1. 3. 1. Структура цеолитов
- 1. 3. 2. Механизм диспропорционирования
- 1. 3. 3. Основные факторы, определяющие процесс диспропорционирования
- 1. 3. 3. 1. Структура цеолита
- 1. 3. 3. 2. Кислотность цеолита
- 1. 3. 3. 3. Условия процесса
- 1. 3. 3. 4. Дезактивация катализаторов
- 1. 3. 4. Промышленные процессы
- 2. 1. Композиты, полученные путем частичной рекристаллизации мезопористого материала
- 2. 2. Композиты, полученные из цеолитных зародышей
- 2. 3. Создание мезопор путем пост-синтетической обработки мезопористых материалов
- 2. 4. Синтез в присутствии инертной мезопористой матрицы
- 2. 5. Рекристаллизация цеолита
- 3. 1. Катализаторы
- 3. 2. Методики физико-химического исследования образцов
- 3. 2. 1. Химический анализ
- 3. 2. 2. Рентгенофазовый анализ
- 3. 2. 3. Низкотемпературная адсорбция азота
- 3. 2. 4. Сканирующая электронная микроскопия
- 3. 2. 5. Просвечивающая электронная микроскопия
- 3. 2. 6. ИК-спектроскопия
- 3. 2. 7. Термопрограммируемая десорбция аммиака
- 3. 3. Методика исследования каталитических свойств
- 3. 3. 1. Методика проведения каталитического эксперимента
- 3. 3. 2. Хроматографический анализ продуктов реакции
- 4. 1. Фазовый состав
- 4. 2. Морфология
- 4. 3. Пористая структура
- 4. 4. Кислотные свойства
- 5. 1. Термодинамический расчет
- 5. 2. Продукты превращения кумола и последовательность их образования
- 5. 3. Кинетика реакции диспропорционирования кумола
- 5. 4. Первичные и вторичные продукты диспропорционирования кумола
- 5. 5. Влияние условий реакции
- 5. 5. 1. Влияние температуры реакции
- 5. 5. 2. Влияние массовой скорости подачи кумола
- 5. 6. Диспропорционироваиие кумола в присутствии п-ДИПБ
- 5. 7. Влияние катализатора
- 5. 7. 1. Влияние состава цеолита (Si/Al)
- 5. 7. 2. Влияние структуры цеолита
- 6. 1. Химический состав
- 6. 2. Фазовый состав
- 6. 3. Морфология
- 6. 4. Пористая структура
- 6. 5. Кислотные свойства
- 6. 5. 1. Количество и сила кислотных центров по данным ТПД аммиака
- 6. 5. 2. Природа кислотных центров по данным ИКС адсорбированного пиридина
- 6. 5. 3. Сила кислотных центров по данным ИКС адсорбированного СО
- 6. 5. 4. Доступность кислотных центров по данным ИКС адсорбированных алкилпиридинов
- 6. 5. 5. Диффузионные свойства по данным ИКС адсорбированного кумола
- 7. 1. Каталитические свойства мезопористых морденитов
- 7. 2. Каталитические свойства мезопористых цеолитов ВЕА
- 7. 3. Стабильность работы мезопористых цеолитов во времени
- 7. 4. Сравнение полученных результатов с литературными данными
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