Планарно-хиральные фосфа-и азапалладациклы неметаллоценового типа: синтез, структура и стереохимия
Диссертация
Однако, в опубликованных ранее обзорах10, 11'121 проблема получения оптически активных производных рСр затрагивается лишь вкратце. Мы попытались восполнить этот пробел и провели анализ имеющихся литературных данных по методам получения планарно-хиральных соединений с рСр-остовом в виде индивидуальных энантио-меров или диастереомеров. Материал классифицирован по принципам разделения энантиомеров… Читать ещё >
Содержание
- I. Введение
- II. Литературный обзор
- Пути получения оптически активных производных [2.2]парациклофана"
- II. 1. Солеобразование 3 П. 1.1. [2.2]Парациклофан-карбоновые кислоты 4 II. 1.2. [2.2]Парациклофанил-замещенные основания
- 11. 2. Ковалентная дериватизация 10 П. 2.1. Карбоннльные соединения
- 11. 2. 2. Карбоновые кислоты
- 11. 2. 3. Гидрокси-производные
- 11. 2. 4. Амино[2.2]парациклофаны
- 11. 2. 5. Сульфоксидные производные рСр
- 11. 3. Координативная дериватизация
- 11. 4. Кинетическое разделение 31 II. 5 Энзиматическое разделение
- II. 6. Разделение энантиомеров и диастереомеров на хиральных колонках
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