Взаимное влияние и реакционная способность адсорбированных атомов и молекул в реакциях CO+O#32#1, H#32#1+O#32#1, NO+H#32#1 на монокристаллах Pd (110) и Pt (111)
Диссертация
Методами ТПР и молекулярных пучков выявлена роль поверхностной реконструкции, приповерхностного кислорода (Оприп), концентрации молекул СОадс в осуществлении реакции низкотемпературного окисления СО на грани Pd (llO). Высокая каталитическая активность Pd в реакции СО + 02 обусловлена легкостью диссоциации молекулярного кислорода. Исследована возможность образования чрезвычайно активных т. н… Читать ещё >
Содержание
- Глава 1. ЛИТЕРАТУРНЫЙ ОБЗОР
- 1. 1. Формы адсорбции Н2, СО, О2, NO, N2O на гранях Pt и Pd
- 1. 2. Механизмы реакций окислительного катализа на платиновых металлах с участием реактантов: Н2, СО, О2, NO, N2O, адсорбированных в молекулярных и диссоциативных формах
- 1. 2. 1. Низкотемпературное окисление оксида углерода в реакциях СО + 02, СО + N
- 1. 2. 2. Окисление водорода
- 1. 2. 3. Окисление водорода оксидом азота
- 1. 3. Применение квантово-химических подходов в изучении механизма элементарных стадий каталитических реакций на металлах платиновой группы: адсорбция и интермедиаты реакций
- C0 + 02, H2+ 02, C0 + N20, N0 + H
- 1. 3. 1. Применение полуэмпирического метода взаимодействующих связей (МВС)
- 1. 3. 2. Применение метода теории функционала плотности (DFT)
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