Исследование электрокаталитических свойств модельных катализаторов на основе Pt, закрепленной на поверхности стеклоуглерода
Диссертация
В качестве топлива в протонобменных топливных элементах может использоваться чистый водород, реформат или метанол. В последнее время рассматриваются альтернативные виды топлива, такие как этанол, этиленгликоль, диметиловый эфир. К сожалению, области применения чистого водорода ограничены (например, при использовании энергии ядерных электростанций, возобновляемых источников, например солнечной… Читать ещё >
Содержание
- Актуальность проблемы
- Цель работы.'
- Научная новизна.*
- Практическая значимость
- Содержание диссертации
- Основные результаты работы
- Апробация работы
- ГЛАВА 1. ЛИТЕРАТУРНЫЙ ОБЗОР
- 1. 1. Электрохемосорбция водорода и кислорода на платине
- 1. 2. Окисление метанола и этиленгликоля на Pt электродах
- 1. 2. 1. Электроокисление метанола на Pt
- 1. 2. 2. Электроокисление этиленгликоля на Pt электрокатализаторах
- 1. 3. Окисление СО на Pt электродах
- 1. 4. Изучение размерных эффектов в электрокатализе
- 1. 4. 1. Основные подходы, используемые для изучения размерного эффекта в электрокатализе.:.'
- 1. 4. 2. Размерный эффект в реакции электровосстановления кислорода
- 1. 4. 3. Размерный эффект в реакции электроокисления СО
- 1. 4. 4. Размерный эффект в реакции электроокисления метанола
- 1. 4. 5. Размерный эффект в реакции электроокисления муравьиной кислоты
- 1. 4. 6. Размерный эффект в реакции электроокисления этиленгликоля
- 1. 5. Приготовление модельных Pt катализаторов
- 1. 5. 1. Основные подходы к приготовлению наноразмерных Pt катализаторов
- 1. 5. 2. Приготовление дисперсных Pt электродов на основе стёклоуглерода
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