Синтез и исследование селективных сорбентов на основе мезопористых мезоструктурированных силикатов MCM-41 и SBA-15
Диссертация
Апробация работы. Основные результаты диссертации докладывались на Международном конгрессе «Цветные металлы» (Красноярск, 2009), четвертой Всероссийской конференции (с международным участием) «Химия поверхности и нанотехнология», (Санкт-Петербург-Хилово, 2009), 6 Всероссийской цеолитной конференции с международным участием «Цеолиты и мезопористые материалы: достижения и перспективы» (Звенигород… Читать ещё >
Содержание
- Список используемых сокращений
- ГЛАВА 1. ЛИТЕРАТУРНЫЙ ОБЗОР
- 1. 1. Мезоструктурированные материалы в качестве носителей
- 1. 2. Строение поверхности силикатных материалов
- 1. 2. 1. Силанольное покрытие
- 1. 2. 2. Поверхностная вода
- 1. 3. Модификаторы и химическое модифицирование
- 1. 4. Методы синтеза органосиликатных композитов
- 1. 5. Сорбция металлов и аминофункциональная прививка
- 1. 6. Сорбция металлов и меркаптофункциональная прививка
- 1. 7. Причины различной способности связывания металлов адсорбентами
- 1. 8. Сорбция Hg (II) из водных растворов
- 1. 9. Адсорбция МПГ
- 1. 10. Десорбция
- ГЛАВА 2. ЭКСПЕРИМЕНТАЛЬНАЯ ЧАСТ
- 2. 1. Синтез мезопористых мезоструктурированных материалов
- 2. 2. Постсинтетическая активация МСМ-41 и SBA
- 2. 3. Методы исследования мезоструктурированных материалов
- 2. 4. Абсолютизация органических растворителей
- 2. 5. Общие экспериментальные принципы химического модифицирования силикатных материалов
- 2. 6. Расчёт количества функционализатора на 1 г носителя
- 2. 7. Синтез АМС
- 2. 7. 1. Иммобилизация у-аминопропилтриметоксисилана на мезопористой матрице
- 2. 7. 2. Синтез M-NH-R: сборка функциональной молекулы на поверхности кремнийсодержащих материалов
- 2. 8. Синтез ММС: прямая иммобилизация у-меркаптопропилтриметоксисилана
- 2. 9. Варьирование условий на стадии подготовки носителя и растворителя к модифицированию
- 2. 10. Варьирование условий функционализации силикатных материалов
- 2. 11. Одностадийный метод синтеза ММС на основе SBA
- 2. 12. Синтез CMC
- 2. 13. Варьирование различных параметров при модифицировании материалов
- 2. 14. Методика сорбции ионов водорода на AMC
- 2. 15. Сорбция ионов Ni (II) на AMC
- 2. 16. Сорбция палладия (П) и ртути (Н) и на полученных сорбентах
- 2. 17. Расчёт коэффициентов уравнения Лэнгмюра
- Глава 3. СИЛАНОЛЬНОЕ ПОКРЫТИЕ
- 3. 1. Постсинтетическая активация мезоструктурированных силикатных материалов МСМ-41 и SBA
- 3. 2. Рентгенографический анализ
- 3. 3. ИК-спектроскопия
- 3. 4. Газовая адсорбция
- 3. 5. Термический анализ
- 3. 6. Моделирование растворения мезоструктурированного материала
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